1. Concept Overview
Temperature is a fundamental physical quantity that determines the degree of hotness or coldness of a body.
It is a measure of the average kinetic energy of the particles (atoms or molecules) in a substance.
When two bodies are in thermal contact:
- Heat flows from the body at higher temperature to the one at lower temperature, until both reach the same temperature.
This condition is known as Thermal Equilibrium.
Thus, temperature acts as an indicator of the direction of heat transfer.
2. Explanation and Mathematical Representation
Definition of Temperature
Temperature is a measure of the average kinetic energy of the particles of a body.
It does not depend on the total energy or mass, but on the average energy per particle.
Mathematically, for an ideal gas:
[
\langle E_t \rangle = \dfrac{3}{2}kT
]
where:
- [\langle E_t \rangle] = average kinetic energy per molecule
- [k] = Boltzmann constant = [1.38 \times 10^{-23} J/K]
- [T] = absolute temperature (in Kelvin)
3. Temperature Scales
Temperature can be measured using various scales. The most common ones are:
- Celsius Scale (°C)
- Fahrenheit Scale (°F)
- Réaumur Scale (°R)
- Kelvin Scale (K) — the absolute scale used in scientific work.
(a) Celsius Scale (°C)
- Defined between the freezing point of water (0°C) and the boiling point of water (100°C) at standard atmospheric pressure.
- The interval between these two fixed points is divided into 100 equal parts, each representing 1°C.
[
T_C = \text{Temperature in Celsius}
]
(b) Fahrenheit Scale (°F)
- Defined between freezing point of water (32°F) and boiling point of water (212°F).
- The interval between these two points is divided into 180 equal parts, each representing 1°F.
[
T_F = \text{Temperature in Fahrenheit}
]
(c) Réaumur Scale (°R)
- Defined between freezing point of water (0°R) and boiling point (80°R).
- Thus, one degree Réaumur is 1/80 of the temperature interval between freezing and boiling points of water.
[
T_R = \text{Temperature in Réaumur}
]
(d) Kelvin Scale (K)
- The Kelvin scale is the absolute scale of temperature.
- It starts from absolute zero (0 K), the point where molecular motion ceases.
- The relation between Celsius and Kelvin is:
[
T_K = T_C + 273.15
]
4. Relationship Between Temperature Scales
Let:
- [T_C] = temperature on Celsius scale
- [T_F] = temperature on Fahrenheit scale
- [T_R] = temperature on Réaumur scale
Then, the ratio of temperature intervals between these scales is:
[\dfrac{T_C – 0}{100}] [= \dfrac{T_F – 32}{180}] [= \dfrac{T_R – 0}{80}]
or simply,
[\dfrac{T_C}{100}] [= \dfrac{T_F – 32}{180}] [= \dfrac{T_R}{80}]
5. Conversion Formulas Between Scales
| Conversion | Formula |
|---|---|
| Celsius → Fahrenheit | [T_F = \dfrac{9}{5}T_C + 32] |
| Fahrenheit → Celsius | [T_C = \dfrac{5}{9}(T_F – 32)] |
| Celsius → Réaumur | [T_R = \dfrac{4}{5}T_C] |
| Réaumur → Celsius | [T_C = \dfrac{5}{4}T_R] |
| Fahrenheit → Réaumur | [T_R = \dfrac{4}{9}(T_F – 32)] |
| Réaumur → Fahrenheit | [T_F = \dfrac{9}{4}T_R + 32] |
| Celsius → Kelvin | [T_K = T_C + 273.15] |
| Kelvin → Celsius | [T_C = T_K – 273.15] |
6. Dimensions and Units
| Quantity | Symbol | Dimensions | SI Unit |
|---|---|---|---|
| Temperature | T | [Θ] | Kelvin (K) |
| Celsius Temperature | T_C | [Θ] | °C |
| Fahrenheit Temperature | T_F | [Θ] | °F |
| Réaumur Temperature | T_R | [Θ] | °R |
7. Key Features
- Temperature measures average kinetic energy of particles.
- Celsius, Fahrenheit, and Réaumur scales are relative, while Kelvin is absolute.
- The ratio of divisions among Celsius : Fahrenheit : Réaumur = 100 : 180 : 80 or 5 : 9 : 4.
- Absolute zero corresponds to [0 , K = -273.15°C = -459.67°F].
- All conversions are linear relationships.
8. Conceptual Questions with Solutions
1. What is temperature?
Temperature is a measure of the average kinetic energy of the molecules in a substance.
2. What happens to molecular motion at absolute zero?
At absolute zero (0 K), molecular motion ceases, and the kinetic energy becomes zero.
3. Define the fixed points on the Celsius scale.
Freezing point of water (0°C) and boiling point of water (100°C) are the fixed points on the Celsius scale.
4. What are the fixed points on the Fahrenheit scale?
Freezing point of water (32°F) and boiling point of water (212°F).
5. How are the Celsius and Fahrenheit scales related?
[\dfrac{T_C}{100} = \dfrac{T_F – 32}{180}] or [T_F = \dfrac{9}{5}T_C + 32]
6. Which temperature scale is absolute?
The Kelvin scale is absolute; it starts at absolute zero.
7. What is the relation between Kelvin and Celsius scales?
[T_K = T_C + 273.15]
8. If temperature is 27°C, find it in Kelvin.
[T_K = 27 + 273.15 = 300.15 \, K]
9. Which temperature scales use the same zero point?
Celsius and Réaumur scales both start at 0° for the freezing point of water.
10. Why is Kelvin used in scientific measurements?
Because it provides an absolute reference where 0 K corresponds to no molecular motion.
11. Convert 68°F to °C.
[T_C = \dfrac{5}{9}(68 – 32) = 20°C]
12. Convert 100°C to °F.
[T_F = \dfrac{9}{5} \times 100 + 32 = 212°F]
13. What is the boiling point of water in Réaumur?
[T_R = \dfrac{4}{5} \times 100 = 80°R]
14. Why is Fahrenheit used in the USA?
It provides finer divisions between freezing and boiling points, making it more sensitive for weather measurement.
15. How do temperature scales differ in increments?
1°C = 1.8°F = 0.8°R
9. FAQ / Common Misconceptions
1. Temperature and heat are the same.
❌ Temperature measures average kinetic energy; heat is energy in transit between bodies.
2. A higher temperature always means more heat.
❌ Not necessarily. Heat depends on both temperature and mass of the substance.
3. 0°C is the coldest temperature possible.
❌ The lowest possible temperature is 0 K (−273.15°C), called absolute zero.
4. Celsius and Kelvin degrees have different sizes.
❌ They have the same interval; the difference is only in the zero point.
5. 0°F is the freezing point of water.
❌ 0°F is lower; water freezes at 32°F.
6. All temperature scales have the same zero.
❌ Each scale has its own reference points and zero.
7. A thermometer measures heat.
❌ It measures temperature, not the total amount of heat.
8. Temperature can be measured in Joules.
❌ No, temperature is measured in Kelvin, Celsius, or Fahrenheit, not energy units.
9. 100°C is the same as 100°F.
❌ 100°C corresponds to 212°F.
10. Absolute zero means no atoms exist.
❌ Atoms still exist but have no kinetic energy.
10. Practice Questions (With Step-by-Step Solutions)
Q1. Convert 25°C to °F and K.
Solution:
[\begin{align*}
T_F &= \dfrac{9}{5}T_C + 32 = \dfrac{9}{5} \times 25 + 32 = 77°F \
T_K &= T_C + 273.15 = 25 + 273.15 = 298.15,K
\end{align*}]
Q2. Convert 300 K to °C and °F.
Solution:
[\begin{align*}
T_C &= T_K – 273.15 = 26.85°C \
T_F &= \dfrac{9}{5} \times 26.85 + 32 = 80.33°F
\end{align*}]
Q3. Find the Celsius temperature equivalent to 68°F.
Solution:
[T_C = \dfrac{5}{9}(68 – 32) = 20°C]
Q4. Convert 40°C to the Réaumur scale.
Solution:
[T_R = \dfrac{4}{5} \times 40 = 32°R]
Q5. Convert 60°R to °C and °F.
Solution:
[\begin{align*}
T_C &= \dfrac{5}{4} \times 60 = 75°C \
T_F &= \dfrac{9}{5} \times 75 + 32 = 167°F
\end{align*}]